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Research Article

A simple approach for extending up to the ultra-relativistic limit the theory of a non-relativistic Fermi gas

[version 1; peer review: 3 not approved]
PUBLISHED 08 Jul 2022
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Abstract

Background: The theory of a Fermi gas constitutes a useful physical model with multiple applications from solid state to stellar physics. The theory of a non-relativistic Fermi gas is relatively simple when compared with the one for a relativistic Fermi gas. Therefore, it would be useful if a rigorous theory of a relativistic Fermi gas could be constructed like the theory of a non-relativistic Fermi gas.

Methods: Such a theory, for T > 0 K, is presented here. It is based on using a recently reported formula for the energies of a relativistic spin-0 particle in a three-dimensional infinite well. The Pauli exclusion principle is used for taking care of the fermion nature of the particles forming a Fermi gas.

Results: A unified description of a Fermi gas at low temperatures is presented. This description is valid from the non-relativistic to the ultra-relativistic limits. Moreover, it is simple. The theory follows the relatively simple approach often used for constructing the theory of a non-relativistic Fermi gas.   

Conclusions: The ultra-relativistic results reported here are often obtained using a different approach than the one used in this work. These results are not new, but they corroborate the correctness of the presented approach. In addition, the relative simplicity of the approach presented in this work allows for teaching the theory of a relativistic Fermi gas in introductory quantum mechanics courses.

Keywords

Quantum Mechanics, Relativistic Quantum Mechanics, Fermi Gas

I. Introduction

The theory of a Fermi gas constitutes a useful model with multiple applications from solid state to stellar physics.13 The theory of a non-relativistic Fermi gas is relatively simple when compared with the one for a relativistic Fermi gas.14 Therefore, it would be useful if a rigorous theory of a relativistic Fermi gas could be constructed like the theory of a non-relativistic Fermi gas.1,2 Building on recently published results for a relativistic Fermi gas at T = 0 K,5 in this work we present such a theory for T > 0 K for the first time.

The theory of a non-relativistic Fermi gas is built from a well-known analytical expression, which gives the energies of a non-relativistic spin-0 particle in a three-dimensional infinite well (particle in a box).1,2 The Pauli exclusion principle is used, in the non-relativistic theory of a Fermi gas at 0 K, for taking care of the fermion nature of the particles forming a Fermi gas.1,2 However, this relatively simple theory cannot be directly extended to the relativistic domain.3,4 This is because no such analytical expression was known, until recently, for the energies of a relativistic spin-0 particle in a box.59 In what follows, first, in Section II is presented a discussion about the energy of a relativistic spin-0 particle in a box when the particle is in a quantum state with positive kinetic energy. In Section III, it is summarized how the energy formula presented in Section II was used for constructing the theory of a relativistic Fermi gas at T = 0 K.5 In Section IV, it is shown that it is possible to construct a theory of a relativistic Fermi gas at T > 0 K but using the same approach often used for constructing the theory of a non-relativistic one. We are then presenting a simple approach for constructing a theory of a Fermi gas valid from the non-relativistic to the ultra-relativistic limits. Finally, the conclusions of this work are given in Section V.

II. Positive energies of a spin-0 particle in a box

A relativistic spin-0 particle with mass m, which is completely confined in a cubic box of size L, only has kinetic energy. The possible positive values of the particle’s energy can be found by solving a special case of the spinless Salpeter equation10,11:

(1)
itψ=γ̂mc2ψ,γ̂=1+p̂2m2c2,p̂=i.

In Eq. (1), c is the speed of the light in vacuum and the wavefunction (ψ) must satisfy null boundary conditions. As it will be shown below, after discounting the energy of the particle associated with its mass (mc2), Eq. (1) can be rewritten as the Poirier-Grave de Peralta equation6,12:

(2)
itψ=p̂2γ̂+1mψ.

When a particle in a box is in a stationary state, it has a constant kinetic energy value, thus a constant value of the square of its linear momentum (p2). Therefore, the solutions of Eq. (2) are exactly equal to the solution of the Grave de Peralta (GdeP) equation69,12:

(3)
itψ=2γ+1m2ψ,γ=1+p2m2c2.

Equation (3) differs from Eq. (2) in that γ is not an operator but a parameter equal to the classical value of the Lorentz factor of special theory of relativity.13 Clearly, Eq. (3) reduces to the Schrödinger equation when γ = 1.1 The infinite-well potential does not interact with the spin degree of freedom; therefore, the energies of a spin-0 and spin-1/2 particle in a cubic box are the same and equal to5,6,14:

(4)
En=π22γ+1mL2n2=γ1mc2,n=nxnynz,nx,y,z=1,2,

In Eq. (4), is the reduced Plank constant,1 and γ is given by the following equation56:

(5)
γ=1+n2π2ƛCL2,ƛC=mc.

In the non-relativistic limit, the reduced Compton wavelength λ/2π << L, thus γ = 1 and Eq. (4) reduces to the well-known formula1,2:

(6)
En=π222mL2n2.

The theory of a non-relativistic Fermi gas, formed by N non-interacting fermions with spin-½, is based on using Eq. (6). The fermion nature of the particles is included by considering the Pauli exclusion principle.1,2 The correct relativistic formula, Eq. (4), was only recently reported.59 Consequently, it can be now used for constructing a theory of a relativistic Fermi gas like the well-known one for a non-relativistic Fermi gas.1,2 This project was started recently.5

It could be helpful noting that Eq. (1) can be obtained by applying the formal first-quantization substitution1,3:

(7)
EĤ=it,pp̂=i.
in the well-known formula of the energy of a classical free particle with mass m which is moving at relativistic speeds with kinetic energy (K), linear momentum p, and total energy E15:
(8)
E=K+mc2=γmc2.

In Eq. (8), γ is the classical Lorentz factor given by Eq. (3). Alternatively, we could start from the following equation, which is equivalent to Eq. (8)6:

(9)
E=p2γ+1m+mc2.

Applying the formal first-quantization substitution to Eq. (9), we obtain6:

(10)
itΩ=2γ̂+1m2Ω+mc2Ω.

In Eq. (10), γ is the operator given by Eq. (1). Now, it is well known in quantum mechanics that applying a constant energy shift to the Hamiltonian gives way to an immaterial time-evolving phase factor in the solution wavefunction. Therefore, Eq. (2) can be obtained from Eq. (10), after replacing Ω as follows6:

(11)
Ωrt=Ψrteimc2t.

For a particle in a box, the solutions of Eq. (2) and (3) are identical. This is because a particle in a box has a constant kinetic energy value when it is in a stationary state; therefore, the particle must also have constant value of the square of its linear momentum (p2) and thus a constant value of γ. Consequently:

(12)
γ̂Ψ=γΨp̂2γ̂+1mψ=p̂2γ+1mψ=.

For instance, if a particle trapped in a one-dimensional box is in a stationary state, then γ is equal to6:

(13)
γ=Ψγ̂Ψ=1+2mc2ESch.

In Eq. (13), ESch is the well-known energy of the corresponding non-relativistic problem1,6:

(14)
ESch=p22m=2k22m,k=πnL,n=1,2,

Note that for a particle in a box the possible values of k are determined by the boundary conditions; thus, k is the same for a non-relativistic and a relativistic particle in a box.6 Consequently, for a particle in a one-dimensional box6:

(15)
γ=1+n2π2ƛCL2,ƛC=mc.

And:

(16)
En=π22γ+1mL2n2=γ1mc2.

Equations (4) and (5) are the tridimensional versions of Eqs. (16) and (15), respectively.

The above discussion is enough for justifying the validity of our approach, which is based on using Eqs. (3) to (5) for constructing a theory of a relativistic Fermi gas. Moreover, it is easy to show that the GdeP equation for any time-independent scalar potential (V):

(17)
itψ=2γ+1m2ψ+.
is equivalent to the Klein-Gordon equation when K > 0. In his case E = K + V, thus:
(18)
E=γ1mc2+V.

Consequently, the classical value of the Lorentz factor (γ) is in general not constant:

(19)
γ=1+EVmc2.

Using Eqs. (7) and (19), we can rewrite the time independent GdeP equation corresponding to Eq. (17) in the following way:

(20)
p̂22mEVEV22mc2ψ=0.

The above equation is an appealing Schrödinger-like form of the time-independent Klein-Gordon equation. Indeed, it is easy to show that by making E′ = E - mc2, Eq. (20) reduces to the well-known expression for the corresponding stationary Klein-Gordon equation (15).

III. Relativistic Fermi gas at T = 0 K

It was recently obtained, using Eq. (4), that the Fermi energy (EF) of a relativistic gas formed by N fermions occupying a volume V is given by the following equation (5):

(21)
EF=23π22/3γ+1mNV2/3,γ=1+3π22/3ƛC2NV2/3.

In the non-relativistic limit (γ ≈ 1) Eq. (21) gives the well-known formula12:

(22)
EF=23π22/32mNV2/3.

This is hardly a surprise because Eq. (21) and Eq. (22) were obtained using the same approach.2,5 However, Eq. (21) also gives the correct result in the ultra-relativistic limit (γ >>1)3,4:

(23)
EF=3π21/3cNV1/3.

This is a well-known formula for a relativistic Fermi gas that was originally obtained following a different approach.3,4 This suggests that a correct theory of a relativistic Fermi gas can be constructing using Eq. (4) and following the relatively simple approach often used for constructing a theory of a non-relativistic Fermi gas.1,2 We will see over and over in this work that it is always the case. For instance, the total energy of a relativistic Fermi gas at 0 K can be obtained from Eq. (4) in the following way5:

(24)
ET=2m3π2V2/30NN2/3γ+1dN.

In the non-relativistic limit Eq. (24) gives the well-known formula2,5:

(25)
ET=35NEF.

In Eq. (25) EF is given by Eq. (22). As expected, Eq. (24) also gives the correct result in the ultra-relativistic limit35:

(26)
ET=34NEF.

In Eq. (26) EF is given by Eq. (23). Consequently, the degeneracy pressure of a non-relativistic (nr) and an ultra-relativistic (ur) Fermi gas at 0 K are15:

(27)
P=ETV=23ETVNV53,nr13ETVNV43,ur.

The possibility of obtaining correct non-relativistic and ultra-relativistic formulas, while using the same theoretical approach, allows for illustrating the effects of the inclusion of special theory of relativity in quantum mechanics. A dramatic example of this is the use of Eqs. (25) and (26) for explaining why Fermi gas stars gravitationally collapse when their masses surpass the Chandrasekhar mass limit.5,16,17

IV. Electronic heat capacity of a relativistic Fermi gas

Often in solid state physics, the non-relativistic theory of a Fermi gas is developed for calculating the electronic heat capacity (Cel) of solids at low temperatures, i.e., when 0 < T < EF/KB, where KB is the Boltzmann constant2:

(28)
Cel=13π2DEFKB2T.

In Eq. (28), D (EF) is the density of states at E = EF2:

(29)
DEF=dNdEEF.

N is obtained from Eq. (21); therefore, using Eqs. (22) and (23) in the non-relativistic and ultra-relativistic limits, respectively; we obtain:

(30)
DEF=32NEF,nr3NEF,ur.

Therefore, from Eqs. (28) and (30) follows:

(31)
CelNkB=π22kBTEF,nrπ2kBTEF,ur.

Again, in both limits, Eq. (31) gives known equations.24 Substituting Eq. (22) in Eq. (31), one obtains24:

(32)
CelNkB=π32/3m5/3kB2Tρ2/3,ρ=mNV.

While substituting Eq. (23) in Eq. (31), we obtain4:

(33)
CelNkB=3π22/33m1/3kBcTρ1/3.

Therefore, in both limits Cel/NKB is proportional to T but the dependence on the density of the gas (ρ) is different.

V. Conclusions

We presented a unified description of a Fermi gas at low temperatures. This description is rigorously valid from the non-relativistic to the ultra-relativistic limits. Moreover, it is simple. The presented theory is based on a recently reported formula for the energies of a relativistic spin-0 particle in a box. The theory follows the relatively simple approach often used for constructing the theory of a non-relativistic Fermi gas. However, the theory outlined here does not include the formation and destruction of particle-antiparticle pairs at energies large than 2mc2. It is then limited to cases where the number of particles can be considered constant.

It is worth noting that the ultra-relativistic results given by Eqs. (23), (26), (27), and (31) are often obtained using a different approach than the one used in this work. These results are not new but, together with the correct deduction of the Chandrasekhar mass limit reported in Ref. [5], they corroborate that the recently reported Eq. (4) is correct and illustrate the practical utility of Eqs. (3) and (17). In addition, the approach presented in this work allows for teaching the theory of a relativistic Fermi gas in introductory quantum mechanics courses.18

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Grave de Peralta L. A simple approach for extending up to the ultra-relativistic limit the theory of a non-relativistic Fermi gas [version 1; peer review: 3 not approved]. F1000Research 2022, 11:761 (https://doi.org/10.12688/f1000research.123275.1)
NOTE: If applicable, it is important to ensure the information in square brackets after the title is included in all citations of this article.
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Version 1
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PUBLISHED 08 Jul 2022
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Reviewer Report 14 Aug 2023
E.F. El-Shamy, Physics, King Khalid University, Abha, Aseer Province, Saudi Arabia 
Not Approved
VIEWS 7
I have carefully reviewed this manuscript. The author presents a unified description of a Fermi gas at low temperatures that remain valid from the nonrelativistic to the ultra-relativistic regimes. The theory developed follows a relatively simple approach commonly used for ... Continue reading
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El-Shamy EF. Reviewer Report For: A simple approach for extending up to the ultra-relativistic limit the theory of a non-relativistic Fermi gas [version 1; peer review: 3 not approved]. F1000Research 2022, 11:761 (https://doi.org/10.5256/f1000research.135363.r171496)
NOTE: it is important to ensure the information in square brackets after the title is included in all citations of this article.
  • Author Response 16 Nov 2023
    Luis Grave de Peralta, Nano Tech Center, Texas Tech University, Lubbock, 79410, USA
    16 Nov 2023
    Author Response
    The author appreciates the opinion of the reviewer, cite "the work appears to be more of a straightforward mathematical exercise rather than a comprehensive exploration of the current state of ... Continue reading
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  • Author Response 16 Nov 2023
    Luis Grave de Peralta, Nano Tech Center, Texas Tech University, Lubbock, 79410, USA
    16 Nov 2023
    Author Response
    The author appreciates the opinion of the reviewer, cite "the work appears to be more of a straightforward mathematical exercise rather than a comprehensive exploration of the current state of ... Continue reading
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Reviewer Report 14 Aug 2023
J. P. W. Diener, Department of Physics and Astronomy, Botswana International University of Science and Technology, Palapye, Central District, Botswana 
Not Approved
VIEWS 5
The article aims to demonstrate an alternative approach to description of a non-relativistic and relativistic Fermi gas. In the conclusion, it is further stated that "...approach presented in this work allows for teaching the theory of a relativistic Fermi gas ... Continue reading
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Diener JPW. Reviewer Report For: A simple approach for extending up to the ultra-relativistic limit the theory of a non-relativistic Fermi gas [version 1; peer review: 3 not approved]. F1000Research 2022, 11:761 (https://doi.org/10.5256/f1000research.135363.r171501)
NOTE: it is important to ensure the information in square brackets after the title is included in all citations of this article.
  • Author Response 16 Nov 2023
    Luis Grave de Peralta, Nano Tech Center, Texas Tech University, Lubbock, 79410, USA
    16 Nov 2023
    Author Response
    The author appreciates the reviewer opinion, cite "the effort of the author to present alternative approaches to what could be considered a standard problem is appreciated." The author also agrees ... Continue reading
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  • Author Response 16 Nov 2023
    Luis Grave de Peralta, Nano Tech Center, Texas Tech University, Lubbock, 79410, USA
    16 Nov 2023
    Author Response
    The author appreciates the reviewer opinion, cite "the effort of the author to present alternative approaches to what could be considered a standard problem is appreciated." The author also agrees ... Continue reading
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Reviewer Report 11 Aug 2022
Niels Benedikter, Department of Mathematics, University of Milan, Milan, Italy 
Not Approved
VIEWS 48
The article considers a semi-relativistic Schrödinger equation (of square-root type) for fermionic particles in a box, computing the heat capacity in the non-relativistic and ultrarelativistic limit.

The work does not represent the state of knowledge completely: the ... Continue reading
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Benedikter N. Reviewer Report For: A simple approach for extending up to the ultra-relativistic limit the theory of a non-relativistic Fermi gas [version 1; peer review: 3 not approved]. F1000Research 2022, 11:761 (https://doi.org/10.5256/f1000research.135363.r147128)
NOTE: it is important to ensure the information in square brackets after the title is included in all citations of this article.
  • Author Response 25 Aug 2022
    Luis Grave de Peralta, Nano Tech Center, Texas Tech University, Lubbock, 79410, USA
    25 Aug 2022
    Author Response
    The author appreciates the “Yes” response of the reviewer to the question “Is the study design appropriate and is the work technically sound? This is because as stated in the ... Continue reading
  • Reviewer Response 09 Sep 2022
    Niels Benedikter, Department of Mathematics, University of Milan, Milan, Italy
    09 Sep 2022
    Reviewer Response
    Equation (1) and its trivial rewriting (2) have already been given by Dirac, Klein, and Fock. As early as 1964, this equation has been given in the textbook on relativistic ... Continue reading
COMMENTS ON THIS REPORT
  • Author Response 25 Aug 2022
    Luis Grave de Peralta, Nano Tech Center, Texas Tech University, Lubbock, 79410, USA
    25 Aug 2022
    Author Response
    The author appreciates the “Yes” response of the reviewer to the question “Is the study design appropriate and is the work technically sound? This is because as stated in the ... Continue reading
  • Reviewer Response 09 Sep 2022
    Niels Benedikter, Department of Mathematics, University of Milan, Milan, Italy
    09 Sep 2022
    Reviewer Response
    Equation (1) and its trivial rewriting (2) have already been given by Dirac, Klein, and Fock. As early as 1964, this equation has been given in the textbook on relativistic ... Continue reading

Comments on this article Comments (0)

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Alongside their report, reviewers assign a status to the article:
Approved - the paper is scientifically sound in its current form and only minor, if any, improvements are suggested
Approved with reservations - A number of small changes, sometimes more significant revisions are required to address specific details and improve the papers academic merit.
Not approved - fundamental flaws in the paper seriously undermine the findings and conclusions
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