Keywords
Quantum Mechanics, Relativistic Quantum Mechanics, Fermi Gas
Quantum Mechanics, Relativistic Quantum Mechanics, Fermi Gas
The theory of a Fermi gas constitutes a useful model with multiple applications from solid state to stellar physics.1–3 The theory of a non-relativistic Fermi gas is relatively simple when compared with the one for a relativistic Fermi gas.1–4 Therefore, it would be useful if a rigorous theory of a relativistic Fermi gas could be constructed like the theory of a non-relativistic Fermi gas.1,2 Building on recently published results for a relativistic Fermi gas at T = 0 K,5 in this work we present such a theory for T > 0 K for the first time.
The theory of a non-relativistic Fermi gas is built from a well-known analytical expression, which gives the energies of a non-relativistic spin-0 particle in a three-dimensional infinite well (particle in a box).1,2 The Pauli exclusion principle is used, in the non-relativistic theory of a Fermi gas at 0 K, for taking care of the fermion nature of the particles forming a Fermi gas.1,2 However, this relatively simple theory cannot be directly extended to the relativistic domain.3,4 This is because no such analytical expression was known, until recently, for the energies of a relativistic spin-0 particle in a box.5–9 In what follows, first, in Section II is presented a discussion about the energy of a relativistic spin-0 particle in a box when the particle is in a quantum state with positive kinetic energy. In Section III, it is summarized how the energy formula presented in Section II was used for constructing the theory of a relativistic Fermi gas at T = 0 K.5 In Section IV, it is shown that it is possible to construct a theory of a relativistic Fermi gas at T > 0 K but using the same approach often used for constructing the theory of a non-relativistic one. We are then presenting a simple approach for constructing a theory of a Fermi gas valid from the non-relativistic to the ultra-relativistic limits. Finally, the conclusions of this work are given in Section V.
A relativistic spin-0 particle with mass m, which is completely confined in a cubic box of size L, only has kinetic energy. The possible positive values of the particle’s energy can be found by solving a special case of the spinless Salpeter equation10,11:
In Eq. (1), c is the speed of the light in vacuum and the wavefunction (ψ) must satisfy null boundary conditions. As it will be shown below, after discounting the energy of the particle associated with its mass (mc2), Eq. (1) can be rewritten as the Poirier-Grave de Peralta equation6,12:
When a particle in a box is in a stationary state, it has a constant kinetic energy value, thus a constant value of the square of its linear momentum (p2). Therefore, the solutions of Eq. (2) are exactly equal to the solution of the Grave de Peralta (GdeP) equation6–9,12:
Equation (3) differs from Eq. (2) in that γ is not an operator but a parameter equal to the classical value of the Lorentz factor of special theory of relativity.13 Clearly, Eq. (3) reduces to the Schrödinger equation when γ = 1.1 The infinite-well potential does not interact with the spin degree of freedom; therefore, the energies of a spin-0 and spin-1/2 particle in a cubic box are the same and equal to5,6,14:
In Eq. (4), is the reduced Plank constant,1 and γ is given by the following equation5–6:
In the non-relativistic limit, the reduced Compton wavelength λ/2π << L, thus γ = 1 and Eq. (4) reduces to the well-known formula1,2:
The theory of a non-relativistic Fermi gas, formed by N non-interacting fermions with spin-½, is based on using Eq. (6). The fermion nature of the particles is included by considering the Pauli exclusion principle.1,2 The correct relativistic formula, Eq. (4), was only recently reported.5–9 Consequently, it can be now used for constructing a theory of a relativistic Fermi gas like the well-known one for a non-relativistic Fermi gas.1,2 This project was started recently.5
It could be helpful noting that Eq. (1) can be obtained by applying the formal first-quantization substitution1,3:
In Eq. (8), γ is the classical Lorentz factor given by Eq. (3). Alternatively, we could start from the following equation, which is equivalent to Eq. (8)6:
Applying the formal first-quantization substitution to Eq. (9), we obtain6:
In Eq. (10), γ is the operator given by Eq. (1). Now, it is well known in quantum mechanics that applying a constant energy shift to the Hamiltonian gives way to an immaterial time-evolving phase factor in the solution wavefunction. Therefore, Eq. (2) can be obtained from Eq. (10), after replacing Ω as follows6:
For a particle in a box, the solutions of Eq. (2) and (3) are identical. This is because a particle in a box has a constant kinetic energy value when it is in a stationary state; therefore, the particle must also have constant value of the square of its linear momentum (p2) and thus a constant value of γ. Consequently:
For instance, if a particle trapped in a one-dimensional box is in a stationary state, then γ is equal to6:
In Eq. (13), ESch is the well-known energy of the corresponding non-relativistic problem1,6:
Note that for a particle in a box the possible values of k are determined by the boundary conditions; thus, k is the same for a non-relativistic and a relativistic particle in a box.6 Consequently, for a particle in a one-dimensional box6:
Equations (4) and (5) are the tridimensional versions of Eqs. (16) and (15), respectively.
The above discussion is enough for justifying the validity of our approach, which is based on using Eqs. (3) to (5) for constructing a theory of a relativistic Fermi gas. Moreover, it is easy to show that the GdeP equation for any time-independent scalar potential (V):
Consequently, the classical value of the Lorentz factor (γ) is in general not constant:
Using Eqs. (7) and (19), we can rewrite the time independent GdeP equation corresponding to Eq. (17) in the following way:
The above equation is an appealing Schrödinger-like form of the time-independent Klein-Gordon equation. Indeed, it is easy to show that by making E′ = E - mc2, Eq. (20) reduces to the well-known expression for the corresponding stationary Klein-Gordon equation (15).
It was recently obtained, using Eq. (4), that the Fermi energy (EF) of a relativistic gas formed by N fermions occupying a volume V is given by the following equation (5):
In the non-relativistic limit (γ ≈ 1) Eq. (21) gives the well-known formula1–2:
This is hardly a surprise because Eq. (21) and Eq. (22) were obtained using the same approach.2,5 However, Eq. (21) also gives the correct result in the ultra-relativistic limit (γ >>1)3,4:
This is a well-known formula for a relativistic Fermi gas that was originally obtained following a different approach.3,4 This suggests that a correct theory of a relativistic Fermi gas can be constructing using Eq. (4) and following the relatively simple approach often used for constructing a theory of a non-relativistic Fermi gas.1,2 We will see over and over in this work that it is always the case. For instance, the total energy of a relativistic Fermi gas at 0 K can be obtained from Eq. (4) in the following way5:
In the non-relativistic limit Eq. (24) gives the well-known formula2,5:
In Eq. (25) EF is given by Eq. (22). As expected, Eq. (24) also gives the correct result in the ultra-relativistic limit3–5:
In Eq. (26) EF is given by Eq. (23). Consequently, the degeneracy pressure of a non-relativistic (nr) and an ultra-relativistic (ur) Fermi gas at 0 K are1–5:
The possibility of obtaining correct non-relativistic and ultra-relativistic formulas, while using the same theoretical approach, allows for illustrating the effects of the inclusion of special theory of relativity in quantum mechanics. A dramatic example of this is the use of Eqs. (25) and (26) for explaining why Fermi gas stars gravitationally collapse when their masses surpass the Chandrasekhar mass limit.5,16,17
Often in solid state physics, the non-relativistic theory of a Fermi gas is developed for calculating the electronic heat capacity (Cel) of solids at low temperatures, i.e., when 0 < T < EF/KB, where KB is the Boltzmann constant2:
In Eq. (28), D (EF) is the density of states at E = EF2:
N is obtained from Eq. (21); therefore, using Eqs. (22) and (23) in the non-relativistic and ultra-relativistic limits, respectively; we obtain:
Therefore, from Eqs. (28) and (30) follows:
Again, in both limits, Eq. (31) gives known equations.2–4 Substituting Eq. (22) in Eq. (31), one obtains2–4:
While substituting Eq. (23) in Eq. (31), we obtain4:
Therefore, in both limits Cel/NKB is proportional to T but the dependence on the density of the gas (ρ) is different.
We presented a unified description of a Fermi gas at low temperatures. This description is rigorously valid from the non-relativistic to the ultra-relativistic limits. Moreover, it is simple. The presented theory is based on a recently reported formula for the energies of a relativistic spin-0 particle in a box. The theory follows the relatively simple approach often used for constructing the theory of a non-relativistic Fermi gas. However, the theory outlined here does not include the formation and destruction of particle-antiparticle pairs at energies large than 2mc2. It is then limited to cases where the number of particles can be considered constant.
It is worth noting that the ultra-relativistic results given by Eqs. (23), (26), (27), and (31) are often obtained using a different approach than the one used in this work. These results are not new but, together with the correct deduction of the Chandrasekhar mass limit reported in Ref. [5], they corroborate that the recently reported Eq. (4) is correct and illustrate the practical utility of Eqs. (3) and (17). In addition, the approach presented in this work allows for teaching the theory of a relativistic Fermi gas in introductory quantum mechanics courses.18
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Is the work clearly and accurately presented and does it cite the current literature?
No
Is the study design appropriate and is the work technically sound?
No
Are sufficient details of methods and analysis provided to allow replication by others?
Yes
If applicable, is the statistical analysis and its interpretation appropriate?
No
Are all the source data underlying the results available to ensure full reproducibility?
No
Are the conclusions drawn adequately supported by the results?
Partly
Competing Interests: No competing interests were disclosed.
Reviewer Expertise: theoretical plasma physics and its applications
Is the work clearly and accurately presented and does it cite the current literature?
No
Is the study design appropriate and is the work technically sound?
No
Are sufficient details of methods and analysis provided to allow replication by others?
Yes
If applicable, is the statistical analysis and its interpretation appropriate?
Not applicable
Are all the source data underlying the results available to ensure full reproducibility?
No source data required
Are the conclusions drawn adequately supported by the results?
No
Competing Interests: No competing interests were disclosed.
Reviewer Expertise: Theoretical nuclear physics, magnetised dense nuclear matter
Is the work clearly and accurately presented and does it cite the current literature?
No
Is the study design appropriate and is the work technically sound?
Yes
Are sufficient details of methods and analysis provided to allow replication by others?
Yes
If applicable, is the statistical analysis and its interpretation appropriate?
Not applicable
Are all the source data underlying the results available to ensure full reproducibility?
No source data required
Are the conclusions drawn adequately supported by the results?
No
References
1. Kothari DS, Singh BN: Thermodynamics of a relativistic Fermi-Dirac gas. Proc. R. Soc. Lond. A. 1942; 180 (983). Publisher Full TextCompeting Interests: No competing interests were disclosed.
Reviewer Expertise: mathematical and theoretical physics, many-body quantum systems, Fermi gas
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